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Variation of surface unevenness of anomalous composite polymer particles produced by the stepwise heterocoagulation of small particles onto large particle by heat treatment
Authors:M Okubo  N Miyachi  Y Lu
Institution:(1) Present address: Department of Industrial Chemistry, Faculty of Engineering, Kobe University, Rokko, 657 Nada, Kobe, Japan
Abstract:Variation of surface unevenness of anomalous composite polymer particles produced by the ldquostepwiserdquo heterocoagulation, which we had suggested in previous articles, of small cationic polymer particles onto large anionic polymer particle (LP) by heat treatment was examined with transmission and scanning electron microscopes. When the anomalous polymer emulsion was kept at higher temperature than the glass transition temperature ofLP, the particle surfaces were continuously changed from uneven to smooth state with the treatment time.Part CXLII of the series of ldquoStudies on Suspension and Emulsionrdquo
Keywords:Anomalous particles  emulsion polymerization  heterocoagulation  composite polymer particles  morphology
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