Reactions of butane and isobutane to CO and CO2 catalyzed by iron oxide treated with sulfate ion |
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| Authors: | M. Hino S. Kobayashi K. Arata |
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| Affiliation: | (1) Hakodate Technical College, Tokura-cho, 042 Hakodate;(2) Hokkaido University of Education, Hachiman-cho, 040 Hakodate, Japan |
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| Abstract: | Catalysts which were obtained by exposing Fe(OH)3 and Fe2O3 prior to the crystallization to 0.5 N H2SO4 and then calcining in air at 500 °C were highly active for oxidations of butane and isobutane to CO and CO2 below 300 °C, while iron oxides prepared without the sulfate treatment were completely inactive.
         ,         Fe(OH)3 Fe2O3    0,5  H2SO4        500 °C  CO CO2, 300 °C,  ,  , .
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