Synthesis and spectroscopic studies of dinuclear copper(II) complexes with new pendant-armed macrocyclic ligands |
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Authors: | Zeng Qingdao Sun Jianjun Gou Shaohua Zhou Keyu Fang Jianglin Chen Hongyuan |
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Institution: | (1) Coordination Chemistry Institute and State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P.R. China |
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Abstract: | Three dinuclear CuII perchlorate complexes of macrocyclic ligands derived from the condensation of sodium 4-X-2,6-diformylphenolate (X=Me, Cl or But) with 1,5-diamino-3-(8-methylquinolyl)azapentane were prepared by in situ transmetallation with Cu(ClO4)2 and characterized by physicochemical, spectroscopic and electrochemical methods. |
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