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Synthesis and spectroscopic studies of dinuclear copper(II) complexes with new pendant-armed macrocyclic ligands
Authors:Zeng  Qingdao  Sun  Jianjun  Gou  Shaohua  Zhou  Keyu  Fang  Jianglin  Chen  Hongyuan
Institution:(1) Coordination Chemistry Institute and State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P.R. China
Abstract:Three dinuclear CuII perchlorate complexes of macrocyclic ligands derived from the condensation of sodium 4-X-2,6-diformylphenolate (X=Me, Cl or But) with 1,5-diamino-3-(8-methylquinolyl)azapentane were prepared by in situ transmetallation with Cu(ClO4)2 and characterized by physicochemical, spectroscopic and electrochemical methods.
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