Highly stereoselective prins cyclization of silylmethyl-substituted cyclopropyl carbinols to 2,4,6-trisubstituted tetrahydropyrans |
| |
| Authors: | Yadav Veejendra K Kumar Naganaboina Vijaya |
| |
| Institution: | Department of Chemistry, Indian Institute of Technology, Kanpur 208 016, India. vijendra@iitk.ac.in |
| |
| Abstract: | The homoallyl cation formed from a cyclopropyl carbinol that was vicinally substituted by a silylmethyl function underwent smooth Prins cyclization with aldehydes and ketones to form 2,4,6-trisubstituted tetrahydropyrans with very high stereoselectivity. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
