Photoelectron spectroscopy of metal β-diketonato complexes |
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Authors: | Igor Novak Branka Kova? |
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Institution: | a Charles Sturt University, P.O. Box 883, Orange NSW 2800, Australia b Physical Chemistry Division, “R. Boškovi?” Institute, HR-10002 Zagreb, Croatia |
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Abstract: | The electronic structures of yttrium(III), gadolinium(III) and ytterbium(III) tris-2,2,6,6-tetramethyl-3,5-heptanedione (tmhd) complexes have been investigated by HeI and HeII photoelectron spectroscopy (UPS), UDFT and OVGF calculations. We discuss metal-ligand bonding in the series of metal β-diketonato complexes on the basis of empirical arguments. The photoionization cross-sections and orbital energies of metal atoms must both be taken into account in order to rationalize changes in relative band intensities of the HeI/HeII spectra. |
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Keywords: | Photoelectron spectroscopy Metal diketonates |
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