A novel application of tin-based alkoxide anion for deacetylation |
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Authors: | Weiying Lin Lingliang long Daiwei Peng Cancheng Guo |
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Affiliation: | College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, PR China |
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Abstract: | A stannylene acetal, in the presence of CsF, is able to cleave both aromatic and aliphatic acetates rapidly and efficiently under room temperature. Control experiments indicate that both the stannylene acetal and CsF are required and play significant roles in the deacetylation process. Thus, it is likely that the tin-based alkoxide anion generated by a stannylene acetal and CsF is responsible for deacetylation. |
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Keywords: | Stannylene acetal Cesium fluoride Alkoxide anion Deacetylation |
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