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Synthesis and characterization of new chiral palladium β-diimine complexes |
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| Authors: | Doris Domin Kurt Mereiter Johannes Fröhlich Karl Kirchner |
| Institution: | a Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria b Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria |
| Abstract: | The synthesis and characterization of a range of chiral β-diimine ligands and their complexes with palladium(II) has been investigated. The introduction of chirality can be easily achieved through a combination of both achiral and chiral building blocks. The absolute configuration of the stereochemical centers has been determined. In addition, representative X-ray structures of both ligands and complexes have been determined. |
| Keywords: | β-Diimines Chiral ligands Palladium(II) Square-planar complexes |
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