A six-coordinate aryl-germanium complex formed by the Kläui ligand |
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| Authors: | Kelly A Davidson |
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| Institution: | Department of Chemistry, University of Waikato, Private Bag 3105, Hamilton, New Zealand |
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| Abstract: | PhGeCl3 reacts with Na{OP(OEt)2]3CoCp} to give the six-coordinate complex PhCl2Ge{OP(OEt)2]3CoCp}, characterised spectroscopically and by an X-ray crystal structure determination which showed a firmly-attached tridentate ligand Ge-O 1.973(2) Å]. |
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| Keywords: | Germanium Six-coordination Klaui ligand X-ray crystal structure NMR |
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