Isolation of donor-stabilized N-silylphosphoranimine cations and the discovery of an ambient temperature route to Poly(alkyl/aryl)phosphazenes |
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| Authors: | Keith Huynh |
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| Institution: | a Davenport Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ont., Canada M5S 3H6
b School of Chemistry, University of Bristol, Bristol BS8 1TS, United Kingdom |
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| Abstract: | This account describes the formation of nitrogen and phosphorus donor-stabilized phosphoranimine cations from N-silylphosphoranimines. A novel phosphine-mediated dehalogenation reaction is also described, as well as the discovery of an ambient temperature route to poly(alkyl/aryl)phosphazenes. |
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