| Synthesis and Crystal Structure of 4,4'-(4-(1-Naphthyl)-4-phenyl-1,3-butadienylidene)-bis[N,N-diethylbenzenamine] |
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| 作者姓名： | LI Xiang-Gao② WU An-Shu XU De-Shun WANG Shi-Rong ZHAO Xue-Ming |
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| 作者单位： | Fine Chemicals Department，School of Chemical Engineering and Technology，Tianjin University，Tianjin 300072，China |
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| 基金项目： | The project was supported by the National 863 Program of China (No. 2002AA325050) |
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| 摘 要： | 1 INTRODUCTION Organic photo-conductors (OPCs), due to their great advantages over inorganic ones, have been widely used in xerography and holography and aroused considerable interest in the past several de- cades. Recently, almost all OPCs are of a layered structure with a thin charge generation layer (CGL) and a charge transport layer (CTL). Current resear- ches are directed to both improving the chara- cteristics of existing OPCs and developing new ma- terials for future applicati…
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Synthesis and Crystal Structure of 4,4'-(4-(1-Naphthyl)-4-phenyl-1,3-butadienylidene)-bis[N,N-diethylbenzenamine] |
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| Abstract: | The title compound (C40H42N2) has been synthesized by the reaction of 1-(1- naphthyl)-1-phenyl-3-chloropropylene and bis(4-(diethylamino) phenyl)methanone, and charac- terized by IR, 1H NMR, MS and X-ray diffraction analysis. The crystal belongs to the monoclinic system, space group P21/c with a = 17.047(3), b = 10.807(2), c = 18.494(4) , β = 105.727(4)°, V = 3279.4(11) 3, Mr = 550.76, Z = 4, Dc = 1.115 g/cm3, μ(MoKα) = 0.085 mm-1, F(000) = 1184, the final R = 0.0625 and wR = 0.1384 for 2276 observed reflections (I > 2σ(Ι)). X-ray analysis reveals that the butadiene fragment adopts a planar cisiod conformation and makes a dihedral angel of 69.4(2)° with the naphthalene ring. |
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| Keywords: | 4 4'-(4-(1-naphthyl)-4-phenyl-1 3-butadienylidene)-bis[N N-diethyl-benzenamine] synthesis crystal structure |
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