| 主客体包结法选择分离白花前胡的化学成分 |
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| 引用本文： | 佟健,王忠华,徐赫男,袁雷,郭放,常键,刘成雁,郭文生.主客体包结法选择分离白花前胡的化学成分[J].化学学报,2007,65(3):222-226. |
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| 作者姓名： | 佟健 王忠华 徐赫男 袁雷 郭放 常键 刘成雁 郭文生 |
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| 作者单位： | (1辽宁大学化学科学与工程学院 沈阳 110036)(2郑州大学化学系 郑州 450052)(3沈阳药科大学制药工程学院 沈阳 110015) (4辽宁省分析测试研究院 沈阳 110015) |
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| 摘 要： | 以1,1,6,6-四苯基-2,4-己二炔-1,6-二醇为主体分子, 可简单、迅速地从白花前胡粗提物中选择分离有效成分3'-乙酰氧基-4'-β-羟基丙酰氧基-3',4'-二氢邪蒿内酯, 收率为0.17%. IR, 1H NMR, 13C NMR光谱和单晶衍射证实了包结化合物的形成及其晶体结构, 并且用气相色谱方法(GC)评价了选择分离效果.
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| 关 键 词： | 白花前胡 包结化合物 选择分离 3'-乙酰氧基-4'-β-羟基丙酰氧基-3' 4'-二氢邪蒿内酯 |
| 收稿时间： | 2006-4-25 |
| 修稿时间： | 2006-04-252006-08-22 |
Selective Isolation of Component of Baihuaqianhu Using Inclusion Crystalline of Host and Guest |
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| TONG,Jian,WANG,Zhong-Hua,XU,He-Nan,YUAN,Lei,GUO,Fang,CHANG,Jian,LIU,Cheng-Yan,GUO,Wen-Sheng.Selective Isolation of Component of Baihuaqianhu Using Inclusion Crystalline of Host and Guest[J].Acta Chimica Sinica,2007,65(3):222-226. |
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| Authors: | TONG Jian WANG Zhong-Hua XU He-Nan YUAN Lei GUO Fang CHANG Jian LIU Cheng-Yan GUO Wen-Sheng |
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| Institution: | (1 Institute of Chemical Science & Engineering, Liaoning University, Shenyang 110036)(2 Department of Chemistry, Zhengzhou University, Zhengzhou 450052)(3 School of Pharmaceutical Engineering, Shenyang Pharmaceutical University, Shenyang 110015)(4 Liaoning Provincial Institute of Analysis Testing and Research, Shenyang 110015) |
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| Abstract: | 3'-Acetoxy-4'-β-hydroxyl-propyloxy-3',4'-dihydroseselin can be selectively isolated from the crude of BAIHUAQIANHU simply and rapidly using 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol as host with yield of 0.17%. Inclusion compound crystal structure was confirmed by IR, 1H NMR, 13C NMR spectra and single crystal X-ray diffraction analysis. GC method was used to assess the isolation effect. |
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| Keywords: | baihuaqianhu inclusion compound selective isolation 3'-acetoxy-4'-β-hydroxyl-propyloxy- 3'4'-dihydroseselin |
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