FOX-7 (1,1-diamino-2,2-dinitroethene): trapped by copper and amines |
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| Authors: | Garg Sonali Gao Haixiang Parrish Damon A Shreeve Jean'ne M |
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| Institution: | Department of Chemistry, University of Idaho, Moscow, Idaho 83844-2343, USA. |
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| Abstract: | Syntheses of the first Cu(NH(3))(2)(FOX)(2) and various Cu(amine)(2)(FOX)(2) (methyl, propyl, and dimethyl amine) complexes were achieved by using metathetical reactions which add a new chapter to the metal chemistry of FOX-7 (1,1-diamino-2,2-dintroethene). The crystal structures of Cu(NH(3))(2)(FOX)(2) and Cu(C(3)H(7)NH(2))(2)(FOX)(2) which show square planar geometry at copper aid in the understanding of the bonding modes in FOX-7 copper complexes which is supported by natural bond orbital (NBO) calculations. Water-free K-FOX was also structured. |
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