A study of the effect of the nature of the solvent and temperature on the route of the reaction of thiobenzyl esters of PIII acids with molecular oxygen |
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| Authors: | Ya. A. Drozdova A. R. Burilov M. A. Pudovik |
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| Affiliation: | (1) tA. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan', Russian Federation |
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| Abstract: | The effects of the nature of the solvents, the degree of dilution, the duration of the process, and the temperature on the ratio of the products obtained in the reactions ofS-benzyl diphenylthiophosphinite or S,S-dibenzyl phenyldithiophosphonite with molecular oxygen have been studied. Possible reaction schemes are discussed.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1444–1445, August, 1993. |
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| Keywords: | thiobenzyl esters of PIII acids solvents degree of dilution isomerization phosphoranyl radicals radical ions complexes |
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