Azonium-Ammonium Tautomerism and Inclusion Complexation of 1-(2,4-diamino phenylazo) Naphthalene and 4-aminoazobenzene |
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Authors: | G?Venkatesh A?Antony?Muthu?Prabhu Email author" target="_blank">N?RajendiranEmail author |
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Institution: | (1) Department of Chemistry, Annamalai University, Annamalai Nagar, 608 002, Tamilnadu, India; |
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Abstract: | Spectral characteristics of 1-(2,4-diamino phenylazo) naphthalene (FBRR, fat brown RR) and 4-aminoazobenzene (AAB) have been
studied in various solvents, varying hydrogen ion concentrations and in β-cyclodextrin (β-CD). The inclusion complex of FBRR
and AAB with β-CD were analysed by UV-visible, fluorometry and CAche-DFT methods. Solvent study reveals that only azo tautomer
is present in both compounds and the large red shifted absorption and emission maxima of FBRR indicate naphthalene ring effectively
increases the π-π* transition. Unusual red shift is observed in acid solutions suggests azonium-ammonium tautomer is present
in both molecules. In β-CD solutions, the large hypsochromic shift is observed in S0 and S1 states indicates ortho amino group of FBRR molecule is entrapped in the β-CD cavity and the large bathochromic shift for AAB in the S1 state indicates 1:1 inclusion complex is formed. |
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