| An Efficient Cationic Cyclization Approach for the Construction of Labdane Diterpenoid Decalin Ring Skeleton |
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| 作者姓名： | JinHuiYANG WeiDongZ.LI |
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| 作者单位： | StateKeyLaboratoryofAppliedOrganicChemistry,LanzhouUniversity,Lanzhou730000 |
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| 摘 要： | An effective approach for the construction of the decalin ring skeleton of labdane diterpenoids was developed based on a key biomimetic cationic polyene cyclization of an epoxy allylsilane precursor. The synthetic approach demonstrated here would be useful in the enantioselective and diastereoselective total synthesis of natural labdane diterpenoids in general.
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| 关 键 词： | 萘烷环 阳离子环化反应 生物合成技术 羟氢氧基 化学结构 |
An Efficient Cationic Cyclization Approach for the Construction of Labdane Diterpenoid Decalin Ring Skeleton |
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| JinHuiYANG WeiDongZ.LI.An Efficient Cationic Cyclization Approach for the Construction of Labdane Diterpenoid Decalin Ring Skeleton[J].Chinese Chemical Letters,2005,16(4):433-436. |
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| Authors: | Jin Hui YANG Wei Dong Z LI State Key Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou |
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| Institution: | Jin Hui YANG,Wei Dong Z. LI* State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000 |
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| Abstract: | An effective approach for the construction of the decalin ring skeleton of labdane diterpenoids was developed based on a key biomimetic cationic polyene cyclization of an epoxy allylsilane precursor. The synthetic approach demonstrated here would be useful in the enantioselective and diastereoselective total synthesis of natural labdane diterpenoids in general. |
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| Keywords: | Allylsilane labdane skeleton cationic cyclization biomimetic synthesis |
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