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功能化碳纳米管与四苯基锌卟啉轴向配位组装(英文)
引用本文:佟履冰,姜 李,孙 剑,尹 桂. 功能化碳纳米管与四苯基锌卟啉轴向配位组装(英文)[J]. 无机化学学报, 2010, 26(11): 1939-1943
作者姓名:佟履冰  姜 李  孙 剑  尹 桂
作者单位:南京大学化学化工学院,南京,210093
摘    要:本文报道了一种基于四苯基锌卟啉与含吡啶基功能化多壁碳纳米管经轴向配位组装。它们被红外光谱、拉曼光谱和透射电镜所表征。荧光光谱研究表明,在该体系中功能化多壁碳纳米管能有效地淬灭卟啉的荧光。

关 键 词:多壁碳纳米管; 卟啉; 轴向配位; 荧光

Supramolecular Self-assembly of Zinc Tetraphenylporphyrin with Functionalized Multi-walled Carbon Nanotubes via Axial Coordination
TONG Lü-Bing,JIANG Li,SUN Jian,YIN Gui. Supramolecular Self-assembly of Zinc Tetraphenylporphyrin with Functionalized Multi-walled Carbon Nanotubes via Axial Coordination[J]. Chinese Journal of Inorganic Chemistry, 2010, 26(11): 1939-1943
Authors:TONG Lü-Bing  JIANG Li  SUN Jian  YIN Gui
Affiliation:School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093,School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093,School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 and School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093
Abstract:Functionalized multi-walled carbon nanotubes (MWCNTs) containing pyridyl group were prepared and characterized by Fourier transform-infrared spectra, Raman spectra and transmission electron microscope. The interaction between the functionalized MWCNTs and zinc tetraphenylporphyrin via axial coordination was investigated by UV-Vis and fluorescence emission spectra. MWCNTs can effectively quench fluorescence of ZnTPP via axial coordination.
Keywords:multi-walled carbon nanotubes   zinc tetraphenylporphyrin   axial coordination   fluorescence
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