The reactivity of 2,2"-bipyridine complexes in the electrochemical reduction of organohalides |
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| Authors: | Yakhvarov D G Samieva E G Tazeev D I Budnikova Yu G |
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| Institution: | (1) Kazan" Research Center, Russian Academy of Sciences, A. E. Arbuzov Institute of Organic and Physical Chemistry, 8 ul. Akad. Arbuzova, 420088 Kazan", Russian Federation;(2) Kazan" State University, 18 ul. Kremlyovskaya, 420008 Kazan", Russian Federation |
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| Abstract: | Nickel(0) complexes coordinatively unsaturated with 2,2"-bipyridine (bpy) are more reactive in the oxidative addition to organic halides than the saturated analogs.  -Organonickel complexes formed as intermediates of catalytic cycles were prepared in high yields using nickel complexes coordinatively unsaturated with bpy and aromatic halides containing a methyl group in the ortho-position of the ring. |
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| Keywords: | nickel 2 2"-bipyridine alkyl halides aryl halides nickel complexes electroreduction catalysis |
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