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The Fourier Transform Raman and infrared spectra of naphthazarin
Affiliation:1. State Key Laboratory of Marine Resource Utilization in South China Sea, Hainan University, China;2. Key Laboratory of Tropical Biological Resources of Ministry of Education, Hainan University, Haikou, Hainan 570228, China;3. Hainan Provincial Key Laboratory for Tropical Hydrobiology and Biotechnology, College of Marine Science, Hainan University, Haikou, Hainan 570228, China;1. School of Chemical Sciences, National Institute of Science Education & Research - Bhubaneswar, P.O: Jatni, Khurda, Odisha, 752050, India;2. Homi Bhabha National Institute, Anushakti Nagar, Mumbai, 400094, India;1. Division of Theoretical Chemistry and Biology, School of Biotechnology, KTH Royal Institute of Technology, 10691, Stockholm, Sweden;2. Tomsk State University, 36 Lenin Avenue, Tomsk, Russia;3. Department of Chemistry and Nanomaterials Science, Bogdan Khmelnitsky National University, Cherkasy, 18031, Ukraine;4. Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Svobodny pr. 79, 660041, Krasnoyarsk, Russia
Abstract:The FT Raman spectra of the three naphthazarin polymorphs have been recorded for the first time and compared with the FTIR spectra of the polymorphs and of naphthazarin with deuterated hydroxyl groups. It is possible to distinguish between the polymorphs, to deduce that the room temperature static symmetry point group of naphthazarin is C2v, to assign the ν(CH), σ(OH), γ(OH) vibrations and to confirm the absence of the ν(OH) mode.
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