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Unsaturated esters of N-(β-hydroxyethyl) lactams
Authors:F P Sidel'kovskaya  F I Ibragimov  M G Zelenskaya  M A Askarov
Institution:(1) Zelinskii Institute of Organic Chemistry AS USSR, Moscow
Abstract:A general method is developed for synthesizing methacrylic esters with a 5-, 6-, or 7-membered lactam ring beta to the carboxyl group, by reacting the sodio-derivatives of the lactams with beta-chloroethyl methacrylate. The esters synthesized are prone to thermal polymerization, and able to copolymerize with other monomers in the presence of azodiisobutyronitrile. The following copolymers are prepared; beta-(N-pyrrolidonyl) ethyl acrylate with methyl acrylate, beta-(N-pyrrolidonyl) ethyl, beta-(N-2-oxotetramethyleneimino) ethyl, and beta-(N-2-oxopentamethyleneimino) ethyl methacrylates withmethyl methacrylate.
Keywords:
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