Formation of chiral quaternary carbon stereocenters using silylene transfer reactions: enantioselective synthesis of (+)-5-epi-acetomycin |
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| Authors: | Calad Stacie A Woerpel K A |
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| Affiliation: | Department of Chemistry, University of California, Irvine, CA 92627-2025, USA. |
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| Abstract: | Chiral quaternary carbon stereocenters can be established with high diastereoselectivity by a silylene transfer/Ireland-Claisen rearrangement. The utility of this method was demonstrated by application to a synthesis of (+)-5-epi-acetomycin. [reaction: see text] |
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