1. Department of Biological Science, Louisiana State University, Baton Rouge, LA 70803, USA;2. Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA 94720, USA;3. Department of Chemistry, University of Washington, Seattle, WA 98195, USA
Abstract:
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Highlights? Esm gene cluster resides on a highly unstable giant plasmid ? EsmA1 and A2 work together to promote the formation of phenazine-1,6-dicarboxylic acid ? Polyketide synthase enzymes EsmB1–B5 catalyze the unique methyl transfer ? Atypical polyketide synthase enzymes EsmD1–D3 catalyze the esterification.
