Complexes of Ge(IV)- and Sn(IV)-fluorides with cyclic and acyclic carbenes: bis(dialkylamino)-difluoromethylenes as carbene sources |
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Authors: | Böttcher Tobias Bassil Bassem S Röschenthaler Gerd-Volker |
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Institution: | School of Engineering and Science, Jacobs University Bremen, Campus Ring 1, 28759 Bremen, Germany. |
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Abstract: | Carbene complexes of Ge(IV)- and Sn(IV)-fluorides have been synthesized by oxidative addition of 2,2-difluoro-1,3-dimethylimidazolidine and bis(dimethylamino)difluoromethane to GeCl(2)?dioxane and SnF(2). Chloride analogs of the Ge(IV) complexes were also isolated. All compounds were characterized in the solid state by single-crystal X-ray diffraction. |
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