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焙烧硼钠钙石在高固液比氯化铵溶液中的溶解动力学
引用本文:GÜR,Aycan.焙烧硼钠钙石在高固液比氯化铵溶液中的溶解动力学[J].物理化学学报,2006,22(10):1287-1290.
作者姓名:GÜR  Aycan
作者单位:Science & Art Faculty, Department of Chemistry, Yüzüncü Yil University, VAN-TURKEY
摘    要:Boron is available in the form of metal borates, especially of sodium and calcium, in nature1]. The production of boron compounds has substantially increased recently due to increasing uses of these compounds in nuclear technology, in rocket engines as f…

收稿时间:2006-04-11
修稿时间:2006-05-23

Dissolution Kinetics of Calcined Ulexite in Ammonium Chloride Solutions at High Solid-to-Liquid Ratios
GR,Aycan.Dissolution Kinetics of Calcined Ulexite in Ammonium Chloride Solutions at High Solid-to-Liquid Ratios[J].Acta Physico-Chimica Sinica,2006,22(10):1287-1290.
Authors:GR  Aycan
Institution:Science & Art Faculty, Department of Chemistry, Yüzüncü Yil University, VAN-TURKEY
Abstract:The dissolution kinetics of calcined ulexite in ammonium chloride solutions at high solid-to-liquid ratios were investigated. In the experiments, calcination temperature, solution concentration, reaction temperature, and prehydration were chosen as parameters. It was observed that the dissolution rate increased with increasing calcination temperature, solution concentration, and reaction temperature, whereas it was not affected by pre-hydration. Employing graphical and statistic methods, the dissolution rate, based on homogeneous reaction model,can be given as: (1-X(B2O3))-1-1=k(c(NH4Cl))1.982t. The activation energy for the dissolution of the ulexite sample calcined at 160 ℃ was found to be
Keywords:Ulexite  Dissolution kinetics  High solid-to-liquid ratios  Ammonium chloride
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