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Complex Formation During Molybdenum Chlorination in DMF Medium |
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| Authors: | Drobot N F Noskova O A Ovchinnikova N A Zvereva G A Larin G M Krenev V A Trifonova E N Drobot D V |
| Institution: | (1) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia;(2) Lomonosov Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia |
| Abstract: | IR and EPR studies of solutions formed after molybdenum chlorination in the medium of DMF revealed the diamagnetic Mo(VI) and paramagnetic Mo(V) complexes of composition R2MoOCl5], where R is (CH3)2NCOH2]+ (I) and (CH3)2NH2]+ (II). The hydrolysis of complex II was found to give dimethyl-substituted ammonium chloride. |
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