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An efficient method for the synthesis of dialkyl chlorophosphates from trialkyl phosphites using bis(trichloromethyl) carbonate
作者姓名:Bo  Wang  Chuan  Ming  Yu  Zhi  Wei  Chen  Wei  Ke  Su
作者单位:College of Pharmaceutical Sciences, Zhejiang University of Technology, Zhejiang Key Laboratory of Pharmaceutical Engineering, Hangzhou 310014, China
基金项目:国家重点基础研究发展计划(973计划),国家自然科学基金
摘    要:A mild and simple method for the synthesis of dialkyl chlorophosphates is described, bis(trichloromethyl) carbonate (BTC) is used as the effective reagent for the conversion of dialkyl phosphites to their corresponding dialkyl chlorophosphates under mild conditions.

关 键 词:氯甲酸三氯甲酯  碳酸盐  二烃基  亚磷酸盐  合成方法

An efficient method for the synthesis of dialkyl chlorophosphates from trialkyl phosphites using bis(trichloromethyl) carbonate
Bo Wang Chuan Ming Yu Zhi Wei Chen Wei Ke Su.An efficient method for the synthesis of dialkyl chlorophosphates from trialkyl phosphites using bis(trichloromethyl) carbonate[J].Chinese Chemical Letters,2008,19(8):904-906.
Authors:Bo Wang  Chuan Ming Yu  Zhi Wei Chen  Wei Ke Su
Institution:College of Pharmaceutical Sciences, Zhejiang University of Technology, Zhejiang Key Laboratory of Pharmaceutical Engineering, Hangzhou 310014, China
Abstract:A mild and simple method for the synthesis of dialkyl clalorophosphates is described, bis(trichloromethyl) carbonate (BTC) is used as the effective reagent for the conversion of dialkyl phosphites to their corresponding dialkyl chlorophosphates under mild conditions.
Keywords:Bis(trichloromethyl) carbonate  Dialkyl chlorophosphate  Trialkyl phosphite  Synthesis
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