| Synthesis, Structure and Properties of (n-Bu_4N)_3[Mo_6O_18NNAr(NO_2)_2] |
| |
| 作者单位： | Department of Chemistry，Lanzhou University，Lanzhou，730000 |
| |
| 摘 要： | The title compound was synthesized and characterized by means of elemental analysis, IR, DTA-TG and UV. Its single crystal structure was solved by using direct methods. The compound crystallizes in the orthorhombic space group Pmc(?) with lattice parameters: a = 1. 7261(2), b=l. 7537(3), c=2. 4258(3) nm. V=7. 34220 nm3, F(000) = 3648, Z = 4. The structure was refined to conventional discrepancy factors of R=0. 060 for 3176 observed reflections [Ⅰ>3σ/(Ⅰ)]. The anion represents a modification of the well-known [Mo6O19]2- anion, in which a single terminal oxo group is replaced by a 2,4-dinitrophenyl hydrazine ligand while the structure integrity of the hexanuclear framework is maintained.
|
Synthesis, Structure and Properties of (n-Bu_4N)_3[Mo_6O_18NNAr(NO_2)_2] |
| |
| WANG Shuang-xi,WANG Xin and ZHAI Ying-li. Synthesis, Structure and Properties of (n-Bu_4N)_3[Mo_6O_18NNAr(NO_2)_2][J]. Chemical Research in Chinese University, 1992, 0(4) |
| |
| Authors: | WANG Shuang-xi WANG Xin ZHAI Ying-li |
| |
| Abstract: | |
| |
| Keywords: | Crystal structure Distortion 2 4-dinitrophenylhydrazine |
| 本文献已被 CNKI 等数据库收录！ |
|
