| 苯并-15-冠-5取代的有机硅化合物的合成及其性能 |
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| 引用本文： | 黄黎明,金道森,陈珊妹. 苯并-15-冠-5取代的有机硅化合物的合成及其性能[J]. 有机化学, 1984, 0(6) |
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| 作者姓名： | 黄黎明 金道森 陈珊妹 |
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| 作者单位： | 中国科学院兰州化学物理研究所，中国科学院兰州化学物理研究所，中国科学院兰州化学物理研究所 |
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| 摘 要： | 我们提出了一条合成含有苯并-15-冠-5取代基的某些有机硅冠醚化合物的简易路线。通过Wittig反应合成的4'-乙烯基苯并-15-冠-5,经过双键上的硅氢加成反应,得到几种新型含有冠醚基团的有机硅烷或氯硅烷。后者可以进一步烷氧基化或者水解成冠醚取代的聚有机硅氧烷。此外,还测定了它们对碱金属离子的络合容量和作为相转移催化剂的能力。
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| 关 键 词： | 冠醚化合物 硅烷(P) 聚硅氧烷 维蒂希反应 加成反应。 |
Synthesis and Properties of Benzo-15-crown-5 Substituted Organosilicon Compounds |
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| Huang Liming,Jin Daosen,Chen Shanmei Lanzhou Institute of Chemical Physics,Academia Sinica. Synthesis and Properties of Benzo-15-crown-5 Substituted Organosilicon Compounds[J]. Chinese Journal of Organic Chemistry, 1984, 0(6) |
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| Authors: | Huang Liming Jin Daosen Chen Shanmei Lanzhou Institute of Chemical Physics Academia Sinica |
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| Abstract: | A simple synthetic route for some benzo-15-crown-5 substituted organosili-con compounds was reported.4'-vinylbenzo-15-crown-5 was prepared by Wittig reactionand then reacted with hydrosilanes in the presence of Pt catalyst to give some new orga-nopolysiloxanes with crown ether substituent.The complex capacity with alkali-metalcations and phase-transfer catalytic activity of some compounds were investigated. |
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| Keywords: | crown ether compounds silane(P) polysiloxane Wittig reaction addition reaction. |
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