| 多取代二乙烯基酮参与的[5C+1X]环合反应研究进展 |
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| 引用本文： | 张大伟,徐显秀,刘群. 多取代二乙烯基酮参与的[5C+1X]环合反应研究进展[J]. 分子科学学报, 2012, 0(1): 1-9 |
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| 作者姓名： | 张大伟 徐显秀 刘群 |
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| 作者单位： | 东北师范大学化学学院;吉林大学农学部 |
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| 基金项目： | 国家自然科学基金资助项目(21172030,20872015);教育部优秀年轻教师基金资助项目(20090404);吉林省青年基金资助项目(20090149) |
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| 摘 要： | 六元环化合物是最常见的环状化合物之一,在许多天然产物和具有生物活性的化合物中存在六元环系,因此其合成方法学的研究一直受到化学工作者的重视.在众多合成方法中,[5+1]环合策略作为一种新颖的方法的研究已越来越多,应用得到进一步拓展.结合二乙烯基酮结构特点,就其参与的[5C+1X]成环反应最新进展做一综述.
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| 关 键 词： | 多取代二乙烯基酮 [5+1]环合反应 六元环 |
Recent progress in the annultation of polysubstituted divinyl ketones |
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| ZHANG Da-wei,XU Xian-xiu,LIU Qun. Recent progress in the annultation of polysubstituted divinyl ketones[J]. Journal of Molecular Science, 2012, 0(1): 1-9 |
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| Authors: | ZHANG Da-wei XU Xian-xiu LIU Qun |
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| Affiliation: | 1(1.Department of Chemistry,Northeast Normal University,Changchun 130024,China; 2.Department of Agriculture,Jilin University,Changchun 130062,China) |
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| Abstract: | Six-membered cycle is the most common motif in the structure of natural products and biologically active compounds.The synthetic methodology of six-membered cycles has attracted much attention of chemists.Among the existing method, annulation is a novel strategy to construct six-membered ring.In this review,the new development of the annultation strategy with polysub stituted divinyl ketones is summarized. |
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| Keywords: | polysubstituted divinyl ketones annulation reaction six-membered ring |
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