| 电化学石英晶体阻抗系统研究金电极上Fe(CN)_6~(3-)/Fe(CN)_6~(4-)电化学过程 |
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| 引用本文： | 谢青季,王进,徐治年,刘宏伟,张友玉,姚守拙. 电化学石英晶体阻抗系统研究金电极上Fe(CN)_6~(3-)/Fe(CN)_6~(4-)电化学过程[J]. 高等学校化学学报, 1999, 0(4) |
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| 作者姓名： | 谢青季 王进 徐治年 刘宏伟 张友玉 姚守拙 |
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| 作者单位： | 湖南师范大学化学研究所 |
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| 基金项目： | 国家自然科学基金,国家教育部留学归国人员基金,湖南省中青年科技基金 |
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| 摘 要： | 电化学过程的石英晶体阻抗分析法已用于现场获取电活性聚合物粘弹性等信息［１，２］．本文联用ＨＰ４３９５Ａ阻抗／网络／频谱分析仪和ＥＧ＆ＧＭ２８３恒电位仪开发出电化学石英晶体阻抗系统（ＥｌｅｃｔｒｏｃｈｅｍｉｃａｌＱｕａｒｔｚＣｒｙｓｔａｌＩｍｐｅｄａｎ...
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| 关 键 词： | 现场动态石英晶体阻抗分析，电化学，K_4Fe（CN）_6，K_3Fe（CN）_6 |
A Study of Electrochemical Process of Fe(CN)3-6/Fe(CN)4-6 on Gold Electrode by Electrochemical Quartz Crystal Impedance System |
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| XIE QingJi,WANG Jin,XU ZhiNian LIU HongWei,ZHANG YouYu,YAO ShouZhuo. A Study of Electrochemical Process of Fe(CN)3-6/Fe(CN)4-6 on Gold Electrode by Electrochemical Quartz Crystal Impedance System[J]. Chemical Research In Chinese Universities, 1999, 0(4) |
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| Authors: | XIE QingJi WANG Jin XU ZhiNian LIU HongWei ZHANG YouYu YAO ShouZhuo |
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| Affiliation: | XIE QingJi*,WANG Jin,XU ZhiNian LIU HongWei,ZHANG YouYu,YAO ShouZhuo |
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| Abstract: | Admittance spectra of quartz crystal resonance were measured in situ in the electrochemical process of Fe(CN)3-6/Fe(CN)4-6 on Au electrode in 10 mol/L Na2SO4 aqueous solution using an electrochemical quartz crystal impedance system. Changes in motional resistance R1 were well reversible with potential, but resonant frequency f0, series resonant frequency fs and parallel resonant frequency fp had significant rising drifts besides somewhat reversible changes with potential. It is concluded that changes in R1 were caused by variations in solution density and viscosity near electrode surface, but frequency responses resulted from both changes of solution properties and corrosion of Au electrode in anodic process. |
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| Keywords: | In situ dynamic quartz crystal impedance analysis Electrochemistry Ferricyanide Ferrocyanide |
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