A bis(trimethylstannyl)amido complex of titanium. The synthesis and structures of [TiCl2(OC6H3Ph2-2,6)2] and [TiCl{N(SnMe3)2}(OC6H3Ph2-2,6)2]期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

A bis(trimethylstannyl)amido complex of titanium. The synthesis and structures of [TiCl2(OC6H3Ph2-2,6)2] and [TiCl{N(SnMe3)2}(OC6H3Ph2-2,6)2]

Affiliation:	1. Polymer Science and Engineering Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-411008, India;2. Membrane Science and Separation Technology Division, CSIR-Central Salt and Marine Chemicals Research Institute, Gijubhai Badheka Marg, Bhavanagar-364002, India;3. Academy of Scientific and Innovative Research (AcSIR), Anusandhan Bhawan, 2 Rafi Marg, New Delhi-110001, India;4. Indian Institute of Science Education and Research, Dr. Homi Bhabha Road, Pune-411008, India

Abstract:	Reaction of TiCl₄ with 2,6-diphenylphenol in toluene gives [TiCl₂(OC₆H₃Ph₂-2,6₂], and this reacts with (Me₃Sn)₃N to give [TiCl{N(SnMe₃)}(OC₆H₃Ph₂-2,6)₂]. The crystals structures of both complexes have been determined.

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