Electrochemical studies on organometallic compounds: XI. Electrogeneration of the zirconium(III) and hafnium(III) anions of zirconocene and hafnocene dichlorides期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Electrochemical studies on organometallic compounds: XI. Electrogeneration of the zirconium(III) and hafnium(III) anions of zirconocene and hafnocene dichlorides

Affiliation:	1. Institute Center for Energy, Masdar Institute, P.O. Box 54224, Abu Dhabi, United Arab Emirates;2. Electrochemical Energy Laboratory, Department of Materials Science & Engineering, Massachusetts Institute of Technology, MA 02139, USA;1. Mineral Resources Research Division, Korea Institute of Geoscience and Mineral Resources (KIGAM), Daejeon, 34132, Republic of Korea;2. Resources Recycling, Korea University of Science and Technology, Daejeon, 34113, Republic of Korea;3. Technology Institute, COSMO ECOCHEM Co., Ulsan, 45010, Republic of Korea

Abstract:	The one-electron reduction of zirconocene and hafnocene dichlorides Cp₂MCl₂ (M = Zr or Hf) yields the corresponding anion Cp₂MCl₂⁻. There is no cleavage of an MCl bond, in contrast to the result in the case of the analogous titanocene and vanadocene dichlorides.

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