Synthesis and variable temperature 31P NMR spectra of the cobalt,rhodium and iridium complexes [M(P(O)(OMe)2)(P(OMe)3)4] (M = Co,Rh, Ir) |
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| Affiliation: | 1. Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, 3012 Bern, Switzerland;2. Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krakow, Poland;1. Department of Physics, Presidency College, Chennai 600005, India;2. Department of Physics, CPCL Polytechnic College, Chennai 600068, India;3. Department of Nuclear Physics, University of Madras, Chennai 600025, India;1. College of Chemistry and Chemical Engineering and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang 471934, PR China;2. Nano-organic Photoelectronic Laboratory and Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China;3. Functional Nano & Soft Materials Laboratory (FUNSOM) and Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, Jiangsu 215123, PR China;1. Crystal Lab, Department of Physics & Astrophysics, University of Delhi, Delhi-7, India;2. Department of Electronics, SGTB Khalsa College, University of Delhi, Delhi-7, India |
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| Abstract: | Syntheses of [M(P(O)(OMe)2)(P(OMe)3)4] (M = Co, Rh, Ir) and variable temperature 31P NMR studies are described, and mechanistic implications discussed. |
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