Polynuclear metal complexes incorporating hydrido-phosphido ligands |
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| Institution: | 1. Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), P. O. Box 45195‐1159, Gavazang, Zanjan 45137‐66731, Iran;2. Research Center for Basic Sciences & Modern Technologies (RBST), Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137‐66731, Iran;3. Department of Chemistry, Faculty of Science, Persian Gulf University, 75169, Bushehr, Iran;4. Nanosensor laboratory, PSG Institute of Advanced Studies, Coimbatore 641 004. India |
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| Abstract: | Addition of phosphines to the coordinatively unsaturated species (Cp)2M2(CO)4 (M = Mo, W) and H2Os3(CO)10 yield a series of products incorporating terminal phosphine along with bridging and capping phosphido ligands formed via insertion into PH bonds. The complexes were characterised by 1H and 31P NMR spectroscopy and mass spectrometry. |
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