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Homogeneous catalytic hydrogenation dicarboxylic acid esters. II
Affiliation:1. Department of Chemistry, Faculty of Arts and Science, Düzce University, 81620 Düzce, Turkey;2. Institute of Chemistry, University of Neuchatel, Avenue de Bellevaux 51, 2000 Neuchatel, Switzerland;3. Institut des Sciences et Ingénierie Chimique, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland;1. Department of Chemistry, Graduate School of Science and Technology, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan;2. Department of Chemistry, School of Education, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan;1. Jagiellonian University, Faculty of Chemistry, Ingardena 3, 30-060 Kraków, Poland;2. Jerzy Haber Institute of Catalysis and Surface Chemistry, PAS, Niezapominajek 8, 30-239 Kraków, Poland;1. Faculty of Chemistry, Kharazmi University, Tehran, Iran;2. Department of Chemistry, Central Tehran Branch, Islamic Azad University, Tehran, Iran;1. Institute of Nanostructured Functional Materials, Huanghe Science and Technology College, Zhengzhou, Henan 450006, China;2. Zhengzhou Research Institute for Abrasive and Grinding Company Limited, Zhengzhou, Henan 450001, China;3. Department of Chemical and Biological Engineering, State University of New York at Buffalo, Buffalo, NY 14260-4200, USA
Abstract:Hydrogenation of dimethyl oxalate in the presence of Ru(CO)2(CH3CO-O)2(PBu3)2 gives methyl glycolate and subsequently ethylene glycol. The formation of the glycol is favoured by hydroxylated solvents.
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