Photoinitiated reactions of allyltriorgano-silanes and -germanes with polyhaloidalkanes. Study of the mechanisms of the reactions by means of the 1H CIDNP method期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Photoinitiated reactions of allyltriorgano-silanes and -germanes with polyhaloidalkanes. Study of the mechanisms of the reactions by means of the 1H CIDNP method

Institution:	1. Normandie Univ, UNIROUEN, INSA Rouen, CNRS, Polymerès, Biopolymères, Surfaces (PBS), 76000 Rouen, France;2. Normandie Univ, UNIROUEN, INSA Rouen, CNRS, Chimie Organique et Bioorganique – Réactivité et Analyse (COBRA), 76000 Rouen, France;1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Murmanska St. 5, Kiev 02660, Ukraine;2. Institute of Bioorganic Chemistry and Petrochemistry National Academy of Sciences of Ukraine, Murmanskaya St. 1, Kiev 02660, Ukraine;3. The Chemours Company, Experimental Station, Bldg. 262, Wilmington, DE 19880, United States;1. Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310058, China

Abstract:	The radical stages in the photolysis reactions of various allyltriorgano-silanes and -germanes (R₃MCH₂CHCH₂; M = Si, Ge) with polyhaloidalkanes have been studied using the ¹H CIDNP method. It has been shown that the mechanism of the photochemical reaction for M = Sn, Ge is different from the case when M = Sn. Some rather stable R₃MCH₂CH(Hal)CH₂R′ (M = Si, Ge) derivatives were isolated and characterized.

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