The synthesis of a novel trimetallic complex containing three redox centres and an assessment of inductive effect transmission through an iron atom |
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| Institution: | 1. Institute of Chemical Sciences, Bahauddin Zakariya University, Multan 60800, Pakistan;2. Centre de Recherche du CHU de Québec-Université Laval, Québec G1V 4G2, Canada;3. Département de Microbiologie-infectiologie et d''immunologie, Faculté de Médecine, Université Laval, Québec G1V 0A6, Canada;4. Centre for Advanced Drug Research, COMSATS University Islamabad, Abbottabad Campus, Abbottabad 22060, Pakistan;5. Natural and Medical Sciences Research Centre, University of Nizwa, P.O. Box 33, PC 616, Birkat Al Mauz, Nizwa, Sultanate of Oman;6. Department of Biology, College of Science, King Khalid University, Abha, Saudi Arabia;7. Department of Zoology, College of Science, Damanhour University, Egypt;8. Department of Biotechnology, Faculty of Science, Bartin University, 74100 Bartin, Türkiye;9. Department of Life Sciences, College of Science and Art Mahyel Aseer, King Khalid University, Abha 62529, Saudi Arabia;10. Department of Pharmaceutical & Medicinal Chemistry, An der Immenburg 4, D-53121 Bonn, Germany |
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| Abstract: | The novel trimetallic complex Fe{η5-C5H4SMo(NO)LCl}2]; in which L = tris(3,5-dimethylpyrazolyl)hydroborate, and its bimetallic analogue {(Mo(NO)LCl)}2(m-S2C6H4)] have been synthesised; electrochemical studies of these compounds indicate that the inductive effects of the molybdenum-containing substituent are transmitted to equal extents through the CFeC and CCC bridging atom chains. |
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