Orthogonal hexatic smectic phase-rare or common? |
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Authors: | Wiesd saw Pyzuk Adam Kr wczy ski Jadwiga Szyd sowska Ewa G recka |
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Institution: |
a Laboratory of Dielectrics and Magnetics, Department of Chemistry, Warsaw Universityx, Warsaw, Poland |
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Abstract: | The hexatic smectic B (Hex B) phase is commonly encountered among hydrogen-bonded liquid crystal materials. Among enaminoketone and Schiff's base compounds, twenty homologous series (c. 102 compounds) exhibiting orthogonal mono-or bi-layer hexatic phases were identified by combined microscopy and DSC. Phase transitions from crystal B (CrB) of Sf to Hex B as well as from Hex B to Sf, Sa or Sc phases were observed within the range 50 to 190°C. Temperature ranges of the Hex B phase detectable by DSC varied from 0.2 to 20°C. Within two groups of three-ring enaminoketones, the formation of the Hex B phase was found to be controlled by both inductive and mesomeric components of the Hammett constants of the terminal substituents of the molecules. |
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