| 消旋的有机二磺酸三邻菲咯啉锌配合物(英) |
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| 引用本文： | 黄雪峰,钱坤.消旋的有机二磺酸三邻菲咯啉锌配合物(英)[J].无机化学学报,2005,21(9):1437-1438. |
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| 作者姓名： | 黄雪峰 钱坤 |
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| 作者单位： | 1. 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093
2. 南昌大学稀土中心,南昌,330013 |
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| 基金项目： | 973项目(No.G2000077500)资助项目 |
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| 摘 要： | Compound Zn(phen)3]BDA] (1) (BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disulfonate, phen= 1,10-phenanthroline) composes of the anion part (racemic-(R,S)-6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disulfonate ) and the cation part which consists of a racemic octahedrally coordinated zinc center defined six nitrogen atoms from three phen rings to form an inorganic chirality that can be resolution by chiral organic ligand, the 3D framework was formed through the strong H-bonding interaction between sulfonate and water. CCDC: 277924.
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| 关 键 词： | 无机手性 6 6′-二溴-2 2′-二甲氧基-1 1′-二萘-4 4′-二磺酸 锌 |
| 文章编号： | 1001-4861(2005)09-1437-02 |
| 收稿时间： | 2005-02-15 |
| 修稿时间： | 6/1/2005 12:00:00 AM |
(△,∧)-[Tris (1,10-phenanthroline)Zn(Ⅱ)][(R,S)-6,6'-dibromo-2,2'-dimethoxy-1,1'-binaphthylene-4,4'-disulfonate] |
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| HUANG Xue-Feng and QIAN Kun.(△,∧)-[Tris (1,10-phenanthroline)Zn(Ⅱ)][(R,S)-6,6''''-dibromo-2,2''''-dimethoxy-1,1''''-binaphthylene-4,4''''-disulfonate][J].Chinese Journal of Inorganic Chemistry,2005,21(9):1437-1438. |
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| Authors: | HUANG Xue-Feng and QIAN Kun |
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| Institution: | Coordination Chemistry Institute,State Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Center of Rare Earth, Nanchang University, Nanchang 330013 |
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| Abstract: | Compound Zn (phen)3] BDA] (1) (BDA =6,6' -dibromo-2,2' -dimethoxy- 1,1' -binaphthylene-4,4' -disulfonate, phen= 1,10-phenanthroline) composes of the anion part (racemic-(R,S)-6,6'-dibromo-2,2'-dimethoxy- 1, 1'binaphthylene-4,4'-disulfonate ) and the cation part which consists of a racemic octahedrally coordinated zinc center defined six nitrogen atoms from three phen rings to form an inorganic chirality that can be resolution by chiral organic ligand, the 3D framework was formed through the strong H-bonding interaction between sulfonate and water. CCDC: 277924. |
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| Keywords: | inorganic chirality 6 6'-dibromo-2 2'-dimethoxy-1 1'-binaphthylene -4 4'-disulfonic Zinc(Ⅱ) |
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