Rhodium(i)-catalysed conjugate phosphination of cyclic alpha,beta-unsaturated ketones with silylphosphines as masked phosphinides |
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| Authors: | Trepohl Verena T Oestreich Martin |
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| Affiliation: | Organisch-Chemisches Institut, Westf?lische Wilhelms-Universit?t, Corrensstrasse 40, D-48149 Münster, Germany. |
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| Abstract: | Nucleophile-activation of the phosphorus(iii)-silicon linkage in silylphosphines generates a nucleophilic phosphorus(iii) equivalent thereby allowing for a rhodium-catalysed conjugate phosphination of beta-substituted alpha,beta-unsaturated acceptors. |
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