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Sulfur ylides
Authors:V K Mavrodiev  I I Furlei  S N Lakeev  F Z Galin  G A Tolstikov
Institution:(1) Institute of Organic Chemistry, Ufa Scientific Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation
Abstract:The mass spectra of negative ions of keto-stabilized sulfur and phosphorus ylides (obtained from amino acids) and products of their thermal conversion are studied. The most characteristic peaks in the mass spectra of ylides belong to negative molecular ions and to M−H] ions. Peaks of fragment ions in the mass spectra of ylides and products of their thermal conversion coincide both in mass numbers and resonance energies. For Part 8, see Ref. 1. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2100–2103, November, 1999.
Keywords:mass spectrometry of negative ions  resonance electron capture  keto-stabilized sulfur and phosphorus ylides  thermal conversion
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