The Host – Guest Interaction Between Cucurbit[7]uril and Ferrocenemonocarboxylic Acid for Electrochemically Catalytic Determination of Glucose |
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Authors: | Yani Tang Shuai Yang Yingying Zhao Min You Fan Zhang Pingang He |
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Affiliation: | Department of Chemistry, East China Normal University, Shanghai 200241, PR China fax/tel: +86‐21‐54340049 |
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Abstract: | A simple and sensitive method for glucose determination was described based on the host‐guest inclusive complex of cucurbit[7]uril and ferrocenemonocarboxylic acid. In this work, the mixture of cucurbit[7]uril and graphene oxide, ferrocenemonocarboxylic acid as electron transfer mediator and glucose oxidase as catalytic material were modified successively on the electrode. Under the optimized conditions, a linear response between current intensity and glucose concentrations over a range of 0.1–10 mM was obtained with a relatively low detection limit (27 µM, S/N=3). Meanwhile, this method exhibited high selectivity in the interference investigation, and the reliability and applicability in human serum samples analysis. |
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Keywords: | Cucurbit[7]uril Ferrocenemonocarboxylic acid Host‐guest interaction Glucose determination Human serum sample |
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