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A Solid Film Electrode of Intermetallic Ag2Hg3.02 for the Direct Determination of Folic Acid in Fresh and Processed Fruit Juices
Authors:Cleide Garcia de Paula  Renata Alves de Toledo  Carlos Manoel Pedro Vaz  Paulo Jorge Marques Cordeiro  José Paschoal Batistuti  Ieda Aparecida Pastre  Hojae Shim  Fernando Luís Fertonani
Affiliation:1. Instituto de Química, Universidade Estadual Paulista, P.?O. Box 355, 14800‐900, Araraquara‐SP, Brazil;2. Embrapa Instrumenta??o Agropecuária, P.?O. Box 741, 13560‐970, S?o Carlos‐SP, Brazil;3. Department of Civil and Environmental Engineering, Faculty of Science and Technology, University of Macau, Macau, SAR, P.?R. China;4. Instituto de Química de S?o Carlos, Universidade de S?o Paulo, Av. Trabalhador S?o‐Carlense, 400, P.?O. Box 780, 13560‐970, S?o Carlos‐SP, Brazil;5. Faculdade de Ciências Farmacêuticas, Universidade Eatadual Paulista, P.?O. Box 355, 14800‐900, Araraquara‐SP, Brazil;6. Instituto de Biociências, Letras e Ciências Exatas, Universidade Eatadual Paulista, Rua C. Colombo, 2265, 15054‐000, S?o José do Rio Preto‐SP, Brazil
Abstract:AgSIE was used for the direct analysis of folic acid (FA), with a detection limit and lower level of quantitation of 6.8×10?10 mol L?1 and 2.3×10?8 mol L?1. The analysis in fresh and processed fruits was done without any sample pretreatment. In strawberry and acerola juices, FA concentration level values were below the method detection limit. FA was detectable in peach (77.7±0.4 µg L?1 and 64.4±0.5 µg L?1), Persian lime (45.4±0.7 µg L?1), pineapple Hawaii (66.2±0.4 µg L?1), pear pineapple (35.3±0.6 µg L?1), cashew (54.4±0.5 µg L?1), passion fruit (73.2±0.3 µg L?1), and apple (84.4±0.5 µg L?1).
Keywords:Folic acid  Fruit juices  SWAdSV  Intermetallic Ag2Hg3.02  SEM  XRD
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