Synthesis of Nitrogen Doped Multilayered Graphene Flakes: Selective Non‐enzymatic Electrochemical Determination of Dopamine and Uric Acid in presence of Ascorbic Acid. |
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| Authors: | Sudip Biswas Rashmita Das Dipanjan Chakraborty Rajib Bandhyopadhyay Panchanan Pramanik |
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| Institution: | 1. Department of Instrumentation and Electronics Engineering, Jadavpur University, Salt Lake Campus, Block LB, Sector III, Salt Lake, Kolkata‐ 700 098, India;2. Department of Physical Science, MCKV Institute of Engineering, Liluah, West Bengal‐711204, India |
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| Abstract: | Nitrogen doped multilayered graphene (NDMLG) is synthesized by annealing the black fluffy mass obtained by decomposing the complex prepared from Zn(OAc)2, diethanolamine and triethanolamine. The NDMLG has been characterized by HRTEM, FESEM, XRD, XPS, Raman spectroscopy, BET which indicate formation of nitrogen doped multilayer graphene flakes with high surface area. NDMLG shows better electrochemical oxidation property towards Dopamine, Uric acid and Ascorbic acid. The linear response ranges for determination of DA, UA and AA are 0.5–150 µM, 3–60 µM and 80–2000 µM respectively and the detection limits (S/N=3) are 15 nM, 15 nM, 580 nM, respectively in the mixture. |
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| Keywords: | Nitrogen doped graphene Diethanolamine Triethanolamine Electrochemical determination Decomposition of Zn complex |
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