| Synthesis and Crystal Structure of α-(3-Phenylureido)-α-(2,4-Dichlorophenyl) Methyl Phenylphosphinic Acid |
| |
| 作者姓名： | ZHOU Jia CHEN Ru-Yu |
| |
| 作者单位： | ZHOU Jia; CHEN Ru-Yu(Institute of Elemento-Organic Chemistry，National Key Laboratory ofElemento-Organic Chemistry，Nankai University，Tainjin 300071)WANG Hong-Gen ;YAO Xin-Kan(Central Laboratory，Nankai University，Tianjin 300071) |
| |
| 摘 要： | 1INThODUCT1ONInaprevi0uspaPer"',wereP0rtedthesyntheses0fsome1,3,4-diazaphospho-lidin-2-thione-4-oxidesandtheirhighselectiveherbicidalactivity.Althoughtherewereseveralreportsaboutthedesulphurisationofsomestraightchainthioureaderiva-tivest2'31,uptonow,thedesulphurisationreactionofcyclicthioureaderivativesutiliz-ingAgNO,-H,Osystemhasnotbeenstudied.InthispaPer,thedesulphurisation0fcis-3,4-diphenyl-5-(2,4-dichlorophenyl)-1,3,4-diazaphOSpholidin-2-thione-4-oasthecyclicsubstrateisrep0rtedfort…
|
Synthesis and Crystal Structure of α-(3-Phenylureido)-α-(2, 4-Dichlorophenyl) Methyl Phenylphosphinic Acid |
| |
| ZHOU Jia, CHEN Ru-Yu.Synthesis and Crystal Structure of α-(3-Phenylureido)-α-(2, 4-Dichlorophenyl) Methyl Phenylphosphinic Acid[J].Chinese Journal of Structural Chemistry,1997(3). |
| |
| Authors: | ZHOU Jia CHEN Ru-Yu |
| |
| Abstract: | The crystal structure of a (3-phenylureido)-a (2, 4-dichlorophenyl)methyl phenylphosphinic acid, C20H17Cl2N2O3P, Mr= 435. 25,which was obtained bydesulphurisation of cis-3, 4-dipheny1-5- (2, 4-dichlorophenyl ) -1, 3, 4-diazaphospholidin2-thione-4-oxide utilizing Ag -H2O system in a yield of 89%, is reported. It crystallizes in orthorhombic space group Pca21 with a= 11. 286(2), b= 20. 601 (4) f c=8. 695(2)A, V= 2021 (1) A3, Z= 4, D.= 1. 430 g/cm3, p=4. 21 cm-1, F(000) =896.The final R factor is 0. 040 and Rw is 0. 045 for 946 unique observed reflectionsI>3a(I)]. The result of X-ray analysis indicates that the molecules in the crystal are linkedtogether by the O(3 ) ...H (2d) - N (2d ) intermolecular hydrogen-bondings. |
| |
| Keywords: | crystal structure desulphurisation reaction 1 3 4-diazaphospholidin-2-thione phosphinic acid derivative |
| 本文献已被 CNKI 等数据库收录！ |
|
