Increased crystal porosity and enhanced gas adsorption by intracolumnar gliding for broadband gas detection |
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| Authors: | Naumov Pance Sakurai Kenji Nukui Akihiko Tanaka Masahiko |
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| Institution: | ICYS, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan. naumov.pance@nims.go.jp |
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| Abstract: | A new three-level structural approach based on anion-induced intracolumnar gliding of stacked coordinatively unsaturated units is described for design of metal-organic crystals which exhibit concentration- and gas-specific adsorption of a variety of small molecules and could be employed for multiple and rapid qualitative and quantitative broadband detection of gases or gaseous mixtures. |
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