| 8 - 乙烯基嘌呤上的亲核加成和环加成反应 |
| |
| 引用本文： | 刘福胜,杨锦宗. 8 - 乙烯基嘌呤上的亲核加成和环加成反应[J]. 有机化学, 2000, 20(2): 189-194 |
| |
| 作者姓名： | 刘福胜 杨锦宗 |
| |
| 作者单位： | 大连理工大学精细化工国家重点实验室,大连,116012 |
| |
| 摘 要： | 研究了8-乙烯基嘌呤与甲醇、苯硫酚和丙二酸二乙酯之间的亲核加成反应以及与环戊二烯之间的环加成反应。合成了8种未见报道的8位取代的嘌呤衍生物，结构均经^1^HNMR、^13^CNMR、^1^H-^1^HNOESY、MS和元素分析确证。
|
| 关 键 词： | 嘌呤P 亲核反应 加成反应 环加成反应 甲醇 苯硫酚 丙二酸乙二酯 环戊二烯 质子磁共振谱法 碳13核磁共振谱法 |
| 修稿时间： | 1998-12-24 |
Nucleophilic addition and cycloaddition to 8 - vinylpurine |
| |
| LIU Fu-Sheng,YANG Jin-Zong. Nucleophilic addition and cycloaddition to 8 - vinylpurine[J]. Chinese Journal of Organic Chemistry, 2000, 20(2): 189-194 |
| |
| Authors: | LIU Fu-Sheng YANG Jin-Zong |
| |
| Affiliation: | LIU Fu-Sheng,YANG Jin-Zong(The State Key laboratory of Fine Chemicals,Ddian University of Technology, 116012 Dalian) |
| |
| Abstract: | The nucleophilic addition reaction between 8 - vinylpurine and mathanol, henzenethiol or diethyl-malonate and the cycloaddition between 8 - vinylpurine and eyclopentadiene has been investigated. A series of 8 - substituted purines which had not been reported before were prepared and characterized by elemental analysis,1H NMR,13 C NMR, 1H-1H NOESY and MS. |
| |
| Keywords: | 8-vinylpurine purine derivative nucleophilic addition cycloaddition |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《有机化学》浏览原始摘要信息 |
|
点击此处可从《有机化学》下载全文 |
