| 乙烯在四氯化亚铜铝甲苯溶液中溶解度测定及其热力学模型 |
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| 引用本文： | 傅旭明,朱自强,朱才铨.乙烯在四氯化亚铜铝甲苯溶液中溶解度测定及其热力学模型[J].物理化学学报,1988,4(4):370-375. |
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| 作者姓名： | 傅旭明 朱自强 朱才铨 |
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| 作者单位： | Chemical Engineering Department; Zhejiang University |
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| 摘 要： | 实测了乙烯在四氯化亚铜铝甲苯溶液中的溶解度。提出了一个处理伴有化学反应的气液平衡的热力学模型, 同时考虑了体系的相平衡和络合平衡, 将Scatchard-Hildebrand模型适当简化后, 计算其液相活度系数, 编制了计算程序, 模型应用方便。用该模型关联计算了溶解度实验数据, 结果令人满意。
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| 收稿时间： | 1986-12-05 |
| 修稿时间： | 1987-06-22 |
THE MEASUREMENT OF THE SOLUBILITY OF ETHYLENE IN CUPROUS ALUMINIUM TETRACHLORIDE SOLUTIONS AND ITS THERMODYNAMIC MODEL |
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| Fu Xuming,Zhu Ziqiang,Zhu Caiquan.THE MEASUREMENT OF THE SOLUBILITY OF ETHYLENE IN CUPROUS ALUMINIUM TETRACHLORIDE SOLUTIONS AND ITS THERMODYNAMIC MODEL[J].Acta Physico-Chimica Sinica,1988,4(4):370-375. |
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| Authors: | Fu Xuming Zhu Ziqiang Zhu Caiquan |
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| Institution: | Chemical Engineering Department; Zhejiang University |
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| Abstract: | The solubility of ethylene in cuprous aluminium tetrachloride-toluene solutions was measured. A thermodynamic model in which phase and complex equilibrium are considered simultaneously was presented. The simplified Scatchard-Hildebrand equation is employed for estimation of activity coefficents of each component. The corresponding computer program was compiled and conveniently used for the correlation of experimental solubility data. The comparison between calculated and experimental values of ethylene solubility gives good agreement.---------------** China Textile University |
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