Reaction of (C6F5)2HGeGeH(C6F5)2 with triethylbismuth: molecular structure of [(C6F5)2Ge]4Bi2 |
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| Authors: | L. V. Pankratov L. N. Zakharov R. I. Bochkova G. K. Fukin Yu. T. Struchkov |
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| Affiliation: | (1) Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600 Nizhnii Novgorod, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | The reaction of (C6F5)2HGeGeH(C6F5)2 with triethylbismuth affords a new polynuclear germylbismuth derivative, [(C6F5Ge]4Bi2 (1). The metal framework of molecule1 has the form of a gable roof built by two central Bi atoms and four peripheral Ge atoms with covalent Bi-Bi bonds [3.045(3) Å], Bi-Ge [2.724(5)-2.755(4) Å] and Ge-Ge [2.444(6), 2.465(6) Å].Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 921–924, May, 1994. |
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| Keywords: | polynuclear compounds, synthesis pentafluorophenyl groups germylbismuth complex, X-ray structural analysis |
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