Peracetylated sugar derivatives show high solubility in liquid and supercritical carbon dioxide |
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Authors: | Potluri Vijay K Xu Jianhang Enick Robert Beckman Eric Hamilton Andrew D |
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Affiliation: | Department of Chemistry, Yale University, PO Box 208107, New Haven, Connecticut 06520-8107, USA. |
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Abstract: | [structure: see text] Acetylated sugars derivatives exhibit high solubility in liquid and supercritical carbon dioxide (scCO(2)). Peracetylated sorbitol and beta-D-galactose are soluble under mild conditions in scCO(2), high pressures are required to dissolve peracetylated beta-cyclodextrin, and peracetoxyalkyl chains impart CO(2)-solubility to amides. |
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