Sulfinyl-mediated chirality transfer in diastereoselective Claisen rearrangements |
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Authors: | Fernández de la Pradilla Roberto Montero Carlos Tortosa Mariola |
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Affiliation: | Instituto de Química Orgánica, CSIC, Juan de la Cierva, 3, 28006 Madrid, Spain. iqofp19@iqog.csic.es |
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Abstract: | [reaction: see text] The highly selective Claisen rearrangements of substrates bearing a sulfinyl moiety at C-5 allow for creation of up to two asymmetric centers and preserve a useful vinyl sulfoxide. |
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